Martensitic stainless steels

Technical data sheets for martensitic stainless steel grades

Definition and applications

Martensitic steels is the smallest family of commercially available stainless steels. Martensitic stainless steel has excellent mechanical properties and is easy to process. Martensitic steel is the only stainless steel that can be subjected to hardening and heat treatment in order to improve its mechanical properties (tensile strength, yield strength and hardness). These steels are used in applications where is required abrasion resistance and hardness (surgical instruments, industrial blades, coating plates, pump components, valve parts, turbine blades, etc.). Martensitic steel is less ductile and with smaller notch strength ratio than ferritic, austenitic and duplex steels. Although many martensitic stainless steels can be welded, preheating and post-welding heat treatments are required. However, these treatments limit martensitic steel from use in welded structures.

Features

Stainless steels are characterized by chromium in variable percentages between 11÷18% and with carbon contents, ranging from low values (0.08%) up to considerable levels (1.20%). Some of these steels contain nickel, but in much lower percentages than the austenitic types (2.5% max).

Due to the high carbon contents, unlike austenitic and ferritic steels, martensitic stainless steels have phase transformation and it is therefore possible to carry out the hardening heat treatment on them, which is useful for improving the mechanical properties, in particular hardness, tensile and yield strength. After quenching, the structure obtained, depending on the carbon content, is martensite or martensite plus carbides. If the final product must be resistant to low temperature, hardening, stress relieving or tempering are required.

Product range

 

Quality – n° steel
EN 10088
AISI Processing routes Supply status Rounds Squares (mm) Flats (mm) Hexagons (mm) Blooms **
X12Cr13
1.4006
410 Peeled Anealed 20-120       100-450
X12Cr13
1.4006
410 Peeled Quenched and tempered 30-450        
X20Cr13
1.4021
420A Cold drawn Quenched and tempered 4-100       100-450
X20Cr13
1.4021
420A Peeled/Turned Quenched and tempered 20-500        
X30Cr13
1.4028
420B Peeled Annealed 20-120        
X30Cr13
1.4028
420B Peeled/Turned Quenched and tempered 20-500        
X46Cr13
1.4034
420C Cold drawn Annealed 5-60        
X46Cr13
1.4034
420C Peeled/Turned Annealed 30-325        
X17CrNi16-2
1.4057
431 Trafilato Quenched and tempered 2-100     11-41  
X17CrNi16-2
1.4057
431 Peeled/Turned Quenched and tempered 20-500        
X17CrNi16-2
1.4057
431 Rolled Quenched and tempered   40-125 30×20-80×20    
X14CrMoS17
1.4104
430F Cold drawn Annealed 1.5-100 5-60   5-60  
X14CrMoS17
1.4104
430F Peeled/Turned Quenched and tempered 40-400        
X14CrMoS17
1.4104
430F Rolled Quenched and tempered   80-100      
X90CrMoV18
1.4112
(440B) Cold drawn Annnealed 4-60        
X90CrMoV18
1.4112
(440B) Peeled/Turned Annealed 30-400        
X39CrMo17-1
1.4122
Cold drawn Quenched and tempered 5-80     17-30  
X39CrMo17-1
1.4122
Peeled/Turned Quenched and tempered 18-500        
X3CrNiMo13-4
1.4313
CA6NM Peeled/Turned Quenched and tempered 20-400        
X4CrNiMo16-5-1
1.4418
Peeled Annealed 25-160        
X4CrNiMo16-5-1
1.4418
Cold drawn Annealed 12-22        
5CrNiCuNb16-4
1.4542
630 Peeled Condition A 30-250        
5CrNiCuNb16-4
1.4542
630 Cold drawn   10-25,4        

*Processing routes peeled/turned with greater tolerance
**Blumi per forgia molati in bianco e atti al taglio in esecuzione “laminato” fino a 200mm, dimensioni superiori in esecuzione “forgiato”.